3.14 - Organic Synthesis Flashcards

1
Q

What compounds take part in hydrolysis?

A
Esters
Polyesters
Polyamides
Alkenes
Halogenoalkanes
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2
Q

What compounds take part in Acid/Base Hydrolysis?

A

Esters
Polyesters
Polyamides

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3
Q

What compound requires Alkaline hydrolysis to form an Alcohol?

A

Halogenoalkane

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4
Q

What reactions require an ethanol solvent?

A

Halogenoalkane |> Primary amine
Halogenoalkane |> Nitrile
Halogenoalkane |> Alkene

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5
Q

What reactions⁺ require KCN followed by H⁺?

A

Forming Hydroxynitriles

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6
Q

What reactions require H₂SO₄?

A

Alcohol |> Ester
Carboxylic Acid |> Ester
Alcohol |> Alkene

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7
Q

Condition for Nucleophilic Addition-Elimination?

A

Room Temp

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8
Q

Condition for NaBH₄?

A

Aqueous, Room Temp

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9
Q

Condition for Nucleophilic Substitution?

A

Heat

Reflux if KCN

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10
Q

Condition for Electrophilic Addition?

A

Room Temp

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11
Q

Reagents & Conditions: Nitrile |> Amine

A

H₂, Ni Catalyst

High Temp & Pressure

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12
Q

Reagents & Conditions: Alkene |> Alcohol

A

Steam & H₃PO₄ Catalyst

300°C, 60 atm

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13
Q

Reagents & Conditions: Nitration of Benzene

A

conc H₂SO₄ & conc HNO₃

50°C

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14
Q

Reagents & Conditions: Reduction of Aminobenzene

A

Tin, conc HCl

Reflux

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15
Q

Reagents & Conditions: Acylation of Benzene

A

RCOCl, AlCl₃

Reflux

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