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Decks in this class (17)
Shapes & Structures 1
Formula for formal charge 1,
Why do en atoms increase shift 2,
For 13c and proton nmr the refere...
77
cards
Organic 1: Nucleophilic addition to the carbonyl group
What does mean 1,
2 main steps of nucleophilic addi...,
Why is the c in c o attacked rath...
9
cards
pKa values
A stronger acid has a pka 1,
For all following acids and pka v...,
Hi 3
20
cards
pKaH values
I 1,
Cl 2,
Hso4 3
18
cards
Shapes & Structures 2
Name the 5 quantum numbers 1,
What does each quantum number rep...,
Orbital energy equation 3
22
cards
Kinetics 1: Rate laws, theories concerning rates
How is rate defined 1,
Why is rate usually expressed as ...,
A b 3
21
cards
Kinetics 2: Experimental derivation of rate laws & constants
Nb collision theory is useful onl...,
Write the rate law of the followi...,
Solve the rate law below between ...
20
cards
Kinetics 3: Obtaining kinetic data
Previous topic requires measuring...,
Blank 2
2
cards
Kinetics 4: Complex reactions: pre-equilibrium, steady state, MM
Define an elementary step 1,
Define kinetic mechanism 2,
Define an elementary reaction 3
27
cards
Kinetics 5: Complex reactions: composite Arrhenius parameters; chain reactions
Composite arhenius parameters 1,
What is a chain reaction 2,
What is a chain carrier 3
10
cards
Kinetics 6: Main recall
Rate constants often vary with te...,
Range of typical values for ea 2,
Value of rt at room temp 3
23
cards
Energetics & Equilibria 1: first law, second law, gas expansions, internal energy, enthalpy, heat capacity, absolute entropy
2nd law of thermodynamics 1,
What are spontaneous reactions 2,
Units of entropy 3
50
cards
Energetics & Equilibria 2: Gibbs energy
Definition of gibbs energy g eq 1,
What is true of g for constant te...,
Show that g decreases for a spont...
25
cards
Energetics & Equilibria 3: Chemical changes
Define the standard state of a su...,
Rho rgo rso 2,
Define fho the standard enthalpy ...
11
cards
Energetics & Equilibria 4: Equilibrium
Write the expressions for the eq ...,
Why do solids and liquids in reac...,
What is true of gibbs energy at e...
15
cards
Energetics & Equilibria 5: Electrochemistry
Cell conventions each half cell i...,
Describe the conventional shortha...,
For the following reaction write 3
31
cards
Energetics & Equilibria 6: Main recall
Expression for weight w 1,
Formula for boltzmann distribution 2,
Entropy is related to the number ...
39
cards
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1A Chemistry
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