symbol for equilibrium
⇌
what is a reversible reaction
a reaction where the products can react together to form the original reactants
what is dynamic equilibrium
Equilibrium in a closed system where the reactions occur at exactly the same rate in each direction
what condition must be satisfied in order to achieve equilibrium
the reversible reaction must take place in a closed system (none of the reactants or products can escape and nothing else can get in)
what does the position of equilibrium depend on
temperature, pressure, concentration
what does it mean if a system is at equilibrium
A system is at equilibrium when both the forward and reverse reactions are happening at exactly the same rate
What is Le Chatelier’s principle?
The idea that if you change the conditions of a reversible reaction at equilibrium, the system will try to counteract that change
what happens when you decrease the temperature of a reversible reaction
if you decrease the temperature, the equilibrium will move in the exothermic direction to produce more heat. so you will get more products for the exothermic reaction
what happens when you increase the temperature of a reversible reaction
if you raise the temperature, the equilibrium will move in the endothermic reaction to try and decrease it. so you will get more products for the endothermic reaction
what equilibrium does pressure effect
equilibrium involving gases
What happens when you increase the pressure in a reversible reaction?
if you increase the pressure, the equilibrium tries to reduce it - it moves in the direction where there are fewer molecules of gas
what happens when you decrease the pressure in a reversible reaction
if you decrease the pressure, the equilibrium tries to increase it - it moves in the direction where there are more molecules of gas
what happens if you change the concentration of either the reactants or the products in an equilibrium
the system responds to bring itself back to equilibrium again.
if you increase the concentration of the reactants the system tries to decrease it by making more products
if you increase the concentration of products the system tries to increase it again by reducing the amount of reactants