What is shielding effect?
It decribes the decreasing attrations between nucleus and an electron
What is the pull from protons called?
Electromagnetic attraction
Why are VE the easiest to be moved away?
Inner electrons shield them from most of the attraction
In the Zeff equation, what are the variable and what do they mean?
Z = the positive attraction from nucleus (# of protons) and S = the shielding effect
What is slaters rule?
It’s basically the Zeff equation
How does shielding effect differ?
It’s 1 for electrons in a lower energy shell, 0.85 for electrons in the same energy shell but lower subshell, and 0.35 for electrons in the same energy shell and subshell
What is the ionic radii of a positive ion?
The radii decreases as there is now a higher Zeff, same Z less S
What is the ionic radii of a negative ion?
The radii increase as there is now a smaller Zeff, same Z more S
What is the definition of ionization energy?
It’s the energy required to remove the high energy electrons from a gaseous atom
What happens during ionization?
Energy is required to remove the electron - IT’S ENDOTHERMIC
Ionization energy values are?
Postive
What is the trend with ionization energy?
Across periods it increases and down groups it decreases
So why does group 15 have a slightly higher IE than group 16?
Look at electron configuration
Group 16 contains one more electron, creating a less favorable arrangement (Group 15’s electron arrangement is more stable)
What is the definition of electronegativity?
The tendency of an atom to attract shared electrons to itself during a chemical bond
What is the trend of electronegativity?
It increases going across the periods and decreases going down a group
What three elements do not form bond?
He, Ne, and Ar SO THEY DO NOT HAVE AN EN value
What is the definition of electron affinity?
The energy change when as electron is added to an atom to make a negative ion
What is the charge of EA?
Negative - energy is released IT’S EXOTHERMIC
What about the EN values for noble gases?
Its very unstable, and it requires an energy input (It’s endothermic)