What theory is used to predict molecular shapes?
Valence Shell Electron Pair Repulsion (VSEPR) theory
What is the basic idea of VSEPR theory?
Electron pairs repel and arrange to maximise separation and minimise repulsion.
How do you calculate the number of electron pairs around a central atom?
Add valence electrons on the central atom + one per attached atom ± charge, then divide by 2
What do you do for a negative charge when calculating electron pairs?
Add one electron for each negative charge.
What do you do for a positive charge when calculating electron pairs?
Remove one electron for each positive charge
What is the electron‑pair arrangement for 2 electron pairs?
Linear
What is the electron‑pair arrangement for 3 electron pairs?
Trigonal planar
What is the electron‑pair arrangement for 4 electron pairs?
Tetrahedral
What is the electron‑pair arrangement for 5 electron pairs?
Trigonal bipyramidal
What is the electron‑pair arrangement for 6 electron pairs?
Octahedral
What shape results from 3 electron pairs but only 2 bonding pairs?
Angular
What shape results from 4 electron pairs but only 3 bonding pairs?
Trigonal pyramidal
What shape results from 6 electron pairs but only 5 bonding pairs?
Square pyramidal
What is the order of electron‑pair repulsions?
Lone pair–lone pair > lone pair–bonding pair > bonding pair–bonding pair
What effect do lone pairs have on molecular shape?
They compress bond angles and distort the shape
What shape is BeCl₂?
Linear
What shape is H₂O?
Angular
What shape is BF₃?
Trigonal planar
What determines the shape of a molecule or polyatomic ion?
The positions of atoms based on electron‑pair arrangement
What is the difference between electron‑pair geometry and molecular shape?
Electron‑pair geometry includes lone pairs; molecular shape considers only bonded atoms
Why do electron pairs adopt specific arrangements?
To minimise repulsion and maximise separation