characteristics of d-block elements
all metallic
high mp and bp
shiny
conduct electricity and heat
what does a half-filled d5 sub-shell and a fully filled d10 sub-shell give to chromium and copper?
additional stability
what happens when d-block elements form positive ions from their atoms?
they lose 4s electrons before losing any 3d electrons
what happens in relation to orbitals when forming an atom from an ion?
4s orbital fills before the 3d orbital
what happens in relation to the orbitals when an ion is formed from an atom?
4s orbital empties before the 3d orbitals
define transition elements
d-block elements that form at least one ion with a partially filled d-orbital
what elements are not classed as transition elements?
zinc and scandium
properties of transition elements which are different from other metals
form compounds in which the transition elements has different oxidation states
form coloured compounds
elements and their compounds can act as catalysts
what do the compounds transition elements form have?
more than one oxidation state
the number of oxidation states… across the transition elements series to manganese and then…
increases
decreases
colour of Fe3+
pale yellow
colour of Mn+2
pale pink
colour of V+2
lilac
what does the colour of a solution with transition elements in link to?
partially filled d orbitals of the transition metal ion and the different oxidation states
what is the catalyst for the haber process?
iron catalyst
what is the catalyst for the production of sulfer trioxide from the oxidation of sulfur dioxide?
vanadium (V) oxide