Unit bonding test study Flashcards

(46 cards)

1
Q

Covalent bonding is electron _________

A

sharing

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2
Q

Covalent bonding occurs because the bonding atom’s elctronegativities are very ______

A

close

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3
Q

Covalent bonding does not form _____, it forms ______

A

Ions, molecules

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4
Q

Covalent bonds are formed between __________

A

non-metals

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5
Q

Shared electrons are called _______, excess electrons are called _________

A

bonding pair, lone pairs

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6
Q

How to draw a covalent compound (Lewis Dot)

A

1) Add up the # of valence electrons in the compound

2) Draw atoms with bonds between them

3) Determine which elements require additional electrons

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7
Q

What elements are drawn in the middle of covalent compounds?

A

Elements with the lowest EN; listed first

(Exception: H)

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8
Q

Sigma bonds

A

line directly connecting two atoms; 1st bonding pair/single bonds

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9
Q

Pi bonds

A

indirect/overlapping bonds connecting atoms

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10
Q

VSEPR

A

Valence Shell Electron Pair Repulsion - used to determine 3D shape of molecules

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11
Q

How do you determine electron geometry?

A

look at how many electron regions surround the central atom

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12
Q

2 electron regions (electron geometry and bond angle)–>

A

Linear, 180

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13
Q

3 electron regions (electron geometry and bond angle)–>

A

Trigonal Planar, 120

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14
Q

4 electron regions (electron geometry and bond angle)–>

A

Tetrahedral, 109.5

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15
Q

How to determine molecular geometry?

A

First determine electron geometry, then determine the number of lone pairs (VSEPR)

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16
Q

Trigonal Planar EG… possible Molecular Geometries?

A

0 lone pairs - trigonal planar
1 lone pair - bent

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17
Q

Tetrahedral EG… possible Molecular Geometries?

A

0 lone pairs - tetrahedral
1 lone pair - trigonal pyramidal
2 lone pairs - bent

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18
Q

How do you name a binary covalent compound?

A

1) Element w/ lower EN first
2) ending of the last element changed to -ide
3) apply proper prefixes

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19
Q

Prefixes…

A

Mono, di, tri, tetra, penta, hexa, hept, oct

Ex: if there is only one of the 1st written element, we do not put mono-

20
Q

If there is no difference in EN, ______ will be formed

A

Non-polar covalent bond (same non-metals)

21
Q

If there is medium difference in EN, ______ will be formed

A

Polar covalent bond (different non-metals)

22
Q

If there is large difference in EN, ______ will be formed

A

ionic bond (metal and non-metal)

23
Q

Polarity is _____

A

uneven charge distribution

24
Q

Least polar type of bond, most polar

25
The atom with greater EN gains a _____ dipole, the atom with lesser EN gains a _____ dipole
negative, positive
26
Polar molecules are called _____
dipoles
27
Molecular polarity is affected by...
bond type and symmetry
28
In a polar covalent bond, asymmetry makes it _____, symmetry makes it _______
a polar molecule, a non-polar molecule
29
Ionic Bonding
The transfer of one or more valence electrons from one atom to another Forms an Anion and Cation
30
Polyatomic Ion
a group of atoms bonded together that has a charge name does not end in -ide (Exceptions: cyanide, peroxide, hydroxide)
31
Transition Metals
Roman numerals show charge
32
Electronegativity General trends
As you go across a period, electronegativity increases As you go down a group, electronegativity decreases Noble gases have the lowest electronegativity
33
Intermolecular (Van der Waals) Forces
Forces that cause molecules to one another due to partial charged poles
34
3 kinds of IMFs ranked by strength
Hydrogen bonds, dipole-dipole forces, london dispersion forces
35
Hydrogen Bonds
Only occur between compounds containing hydrogen with N, O, or F
36
Dipole-dipole force
due to permanent partial charges on dipoles
37
London dispersion forces
occurs in molecules which would otherwise be non-polar - slight temporary imbalances in electron structure
38
Chemical bonds
Bonded atoms have lower energy than single atoms bond forms - exothermic bond breaks - endothermic
39
metallic bonds
formed between the attraction of mobile valence electrons and positive ions - mobile electrons good conductivity, malleable, and ductile Element symbol
40
properties of metallic bond
high boiling point very hard always conductive not soluble
41
properties of ionic bond
high boiling point very hard not conductive as a solid high solubility
42
properties of a covalent bond
low boiling point soft never conductive low solubility
43
network solids
large macromolecules - graph paper atoms covalently bonded together in a continous fashion
44
properties of a network solid
high boiling point very hard not conductive ex: diamond
45
Exothermic
Bond forms - releases more energy than is absorbed (more KE less PE)
46
Endothermic
Bond breaks - absorbs more energy than is released (more PE less KE)